Molecule image

inm5Um

Summary

Full name5-(isopentenylaminomethyl)-2′-O-methyluridine
Short nameinm5Um
New Nomenclature0583U
RNAMods abbreviation¼
Enzymes
Found in phylogeny
Found in RNA
SMILESCOC1C(O)C(CO)OC1N2C=C(CNCC=C(C)C)C(=O)NC2=O
SMILES (no stereochemical information)COC1C(O)C(CO)OC1N2C=C(CNCC=C(C)C)C(=O)NC2=O

LC-MS Information

Sum formulaC16H25N3O6
Monoisotopic mass355.1743
Average mass355.3911
[M+H]+356.1821
Product ions210
Normalized LC elution time * not available
LC elution order/characteristics not available

* normalized to guanosine (G), measured with a RP C-18 column with acetonitrile/ammonium acetate as mobile phase.

3D Molecule representation

Download [.mol file for inm5Um]

Comments

5-(isopentenylaminomethyl)uridine and 2-thio-5-(isopentenylaminomethyl)uridine were identified in tRNA of Thermodesulfobacterium commune. Their identities were determined by mass spectrometry and confirmed by chemical synthesis. Data were presented at the tRNA meeting in Banz, Germany (1985) by P.F. Crain, D.R. Phillips, T. Hashizume and F. Widdel. Since then, beside the Banz-meeting abstract, no paper was published about these modified nucleosides.

Reactions producing 5-(isopentenylaminomethyl)-2′-O-methyluridine

Name
inm5U:inm5Um

Last modification of this entry: Oct. 6, 2017

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