Full name: | tRNA uridine(34) 5-carboxymethylaminomethyl synthesis enzyme |
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Synonym: | GidA, TrmF |
GI: | 62288115 |
Orf: | b3741 |
COG: | COG0445 |
UniProt: | P0A6U3 |
Structures: | | 3CP2 | 3CES | |
Alpha Fold Predicted Structure: | AF-P0A6U3-F1 |
Complex: | MnmG/MnmE |
Enzyme type: | other |
Position of modification - modification: |
t:34 - cmnm5s2U t:34 - mnm5s2U t:34 - cmnm5Um t:34 - mnm5U |
Title: | |
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Classification: | |
Technique: | |
Pdb Files | 3CES.pdb   3CP2.pdb   |
Pdbx/mmCIF Files | 3CES.cif   3CP2.cif   |
MFYPDPFDVIIIGGGHAGTEAAMAAARMGQQTLLLTHNIDTLGQMSCNPAIGGIGKGHLVKEVDALGGLMAKAIDQAGIQFRILNASKGPAVRATRAQADRVLYRQAVRTALENQPNLMIFQQAVEDLIVENDRVVGAVTQMGLKFRAKAVVLTVGTFLDGKIHIGLDNYSGGRAGDPPSIPLSRRLRELPLRVGRLKTGTPPRIDARTIDFSVLAQQHGDNPMPVFSFMGNASQHPQQVPCYITHTNEKTHDVIRSNLDRSPMYAGVIEGVGPRYCPSIEDKVMRFADRNQHQIFLEPEGLTSNEIYPNGISTSLPFDVQMQIVRSMQGMENAKIVRPGYAIEYDFFDPRDLKPTLESKFIQGLFFAGQINGTTGYEEAAAQGLLAGLNAARLSADKEGWAPARSQAYLGVLVDDLCTLGTKEPYRMFTSRAEYRLMLREDNADLRLTEIGRELGLVDDERWARFNEKLENIERERQRLKSTWVTPSAEAAAEVNAHLTAPLSREASGEDLLRRPEMTYEKLTTLTPFAPALTDEQAAEQVEIQVKYEGYIARQQDEIEKQLRNENTLLPATLDYRQVSGLSNEVIAKLNDHKPASIGQASRISGVTPAAISILLVWLKKQGMLRRSA
Proteins MnmE and MnmG are evolutionary conserved from bacteria to eukaryotic organelles. MnmE and MnmG are dimeric and form a functional α2β2 heterotetrameric complex (MnmEG) in which both proteins are interdependent. MnmG is a FAD- and NADH-binding protein, while instead, MnmE is a GTP- and tetrahydrofolate (THF)-binding protein. The MnmEG heterotetrameric complex catalyzes the addition of the aminomethyl (nm) and carboxymethylaminomethyl (cmnm) groups to position 5 of the wobble uridine using ammonium and glycine, respectively. In E.coli MnmEG complex is involved in the modification of the wobble uridine of tRNALysmnm5s2UUU, tRNAGlncmnm5s2UUG, tRNAArgmnm5UCU, tRNAGlumnm5s2UUC, tRNALeucmnm5UmAA, tRNAGlymnm5UCC. MNMEG modified substrates are neither the starting nor the final products of the catalytic pathway. Indeed, MnmA is involved in the 2-thiolation of the wobble uridine after which MnmEG complex is involved (Moukadiri et al. 2014 ) .
Reaction | Substrate | SubstrateType | Position | (Anti)Codon | Modified (Anti)Codon | Amino Acid Change | Transcript Name | Transcript Region | Cellular Localization | References |
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s2U:cmnm5s2U | RNA | tRNA | 34 | 2UU | $UU | tRNALys2UU | wobble - position | Prokaryotic Cytosol | 24293650    | |
s2U:nm5s2U | RNA | tRNA | 34 | 2UU | ∫UU | tRNALys2UU | wobble - position | Prokaryotic Cytosol | 24293650    | |
s2U:nm5s2U | RNA | tRNA | 34 | 2UC | ∫UC | tRNAGlu2UC | wobble - position | Prokaryotic Cytosol | 24293650    | |
s2U:cmnm5s2U | RNA | tRNA | 34 | 2UC | $UC | tRNAGlu2UC | wobble - position | Prokaryotic Cytosol | 24293650    | |
s2U:nm5s2U | RNA | tRNA | 34 | 2UG | ∫UG | tRNAGln2UG | wobble - position | Prokaryotic Cytosol | 24293650    | |
s2U:cmnm5s2U | RNA | tRNA | 34 | 2UG | $UG | tRNAGln2UG | wobble - position | Prokaryotic Cytosol | 24293650    | |
s2U:nm5s2U | RNA | tRNA | 34 | 2AA | ∫AA | tRNALeu2AA | wobble - position | Prokaryotic Cytosol | 24293650    | |
s2U:cmnm5s2U | RNA | tRNA | 34 | 2AA | $AA | tRNALeu2AA | wobble - position | Prokaryotic Cytosol | 24293650    | |
s2U:nm5s2U | RNA | tRNA | 34 | 2CU | ∫CU | tRNAArg2CU | wobble - position | Prokaryotic Cytosol | 24293650    | |
s2U:cmnm5s2U | RNA | tRNA | 34 | 2CU | $CU | tRNAArg2CU | wobble - position | Prokaryotic Cytosol | 24293650    | |
s2U:nm5s2U | RNA | tRNA | 34 | 2CC | ∫CC | tRNAGly2CC | wobble - position | Prokaryotic Cytosol | 24293650    | |
s2U:cmnm5s2U | RNA | tRNA | 34 | 2CC | $CC | tRNAGly2CC | wobble - position | Prokaryotic Cytosol | 24293650    |
Alpha Fold Pdb Files | AF-P0A6U3-F1.pdb   |
Alpha Fold Pdbx/mmCIF Files | AF-P0A6U3-F1.cif   |
DSSP Secondary Structures | P0A6U3.dssp   |
Title | Authors | Journal | Details | ||
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Further insights into the tRNA modification process controlled by proteins MnmE and GidA of Escherichia coli. | Yim L, Moukadiri I, Bjork GR, Armengod ME | Nucleic Acids Res | [details] | 17062623 | - |
Crystal structures of the conserved tRNA-modifying enzyme GidA: implications for its interaction with MnmE and substrate. | Meyer S, Scrima A, Versées W, Wittinghofer A | J Mol Biol | [details] | 18565343 | - |
Translational misreading: a tRNA modification counteracts a +2 ribosomal frameshift. | Brégeon D, Colot V, Radman M, Taddei F | Genes Dev | [details] | 11544186 | - |
Evolutionarily conserved proteins MnmE and GidA catalyze the formation of two methyluridine derivatives at tRNA wobble positions. | Moukadiri I, Prado S, Piera J, Velázquez-Campoy A, Björk GR, Armengod ME | Nucleic Acids Res | [details] | 19767610 | - |
Enzymology of tRNA modification in the bacterial MnmEG pathway. | Armengod ME, Moukadiri I, Prado S, Ruiz-Partida R, Benitez-Paez A, Villarroya M, Lomas R, Garzon MJ, Martinez-Zamora A, Meseguer S, Navarro-Gonzalez C | Biochimie | [details] | 22386868 | - |
The output of the tRNA modification pathways controlled by the Escherichia coli MnmEG and MnmC enzymes depends on the growth conditions and the tRNA species. | Moukadiri I, Garzon MJ, Bjork GR, Armengod ME... | Nucleic Acids Res | [details] | 24293650 | - |
SAXS analysis of the tRNA-modifying enzyme complex MnmE/MnmG reveals a novel interaction mode and GTP-induced oligomerization. | Fislage M, Brosens E, Deyaert E, Spilotros A, Pardon E, Loris R, Steyaert J, Garcia-Pino A, Versees W... | Nucleic Acids Res | [details] | 24634441 | - |
_PubMed_ |
_EcoCyc_ |