Full name: | tRNA (guanine-N(1)-)-methyltransferase |
---|---|
GI: | 731672 |
Orf: | YHR070W |
COG: | COG2520 |
UniProt: | P38793 |
Alpha Fold Predicted Structure: | AF-P38793-F1 |
Enzyme type: | methyltransferase |
Position of modification - modification: |
t:37 - yW t:37 - m1I t:37 - m1G |
MKIALPVFQKFNRLISSCKMSGVFPYNPPVNRQMRELDRSFFITKIPMCAVKFPEPKNISVFSKNFKNCILRVPRIPHVVKLNSSKPKDELTSVQNKKLKTADGNNTPVTKGVLLHESIHSVEDAYGKLPEDALAFLKENSAEIVPHEYVLDYDFWKAEEILRAVLPEQFLEEVPTGFTITGHIAHLNLRTEFKPFDSLIGQVILDKNNKIECVVDKVSSIATQFRTFPMKVIAGKSDSLVVEQKESNCTFKFDFSKVYWNSRLHTEHERLVKQYFQPGQVVCDVFAGVGPFAVPAGKKDVIVLANDLNPESYKYLKENIALNKVAKTVKSFNMDGADFIRQSPQLLQQWIQDEEGGKITIPLPLKKRHRSQQHNDQQPPQPRTKELIIPSHISHYVMNLPDSAISFLGNFRGIFAAHTKGATDTIQMPWVHVHCFEKYPPGDQVTEDELHARVHARIIAALKVTADDLPLNAVSLHLVRKVAPTKPMYCASFQLPANV
S-Adenosyl methionine (SAM or AdoMet) consists of an adenosyl cation attached to the sulfur methionine. It is synthesized from ATP and methionine by S-Adenosylmethionine synthetase enzyme through the reaction of ATP with L-methionine and water forming as catalytical product S-adenosyl-L-methionine. SAM is a common cosubstrate involved in several reactions, among which methyl group transfers. Trm5 is a site-specific enzyme methylating the N1 position of guanosine-37 in various cytoplasmic and mitochondrial tRNAs using SAM as a cosubstrate ( Lee et al. 2007). Methylation is not dependent on the nature of the nucleoside 5' of the target nucleoside. This is the first step in the biosynthesis of wybutosine (yW), a modified base adjacent to the anticodon of tRNAs and required for accurate decoding ( Björk et al. 2001). It also methylates I at position 37.
Reaction | Substrate | SubstrateType | Position | (Anti)Codon | Modified (Anti)Codon | Amino Acid Change | Transcript Name | Transcript Region | Cellular Localization | References |
---|---|---|---|---|---|---|---|---|---|---|
G:m1G | RNA | tRNA | 37 | UAG | UAG | tRNALeuUAG | anticodon-loop | Nucleus | ||
G:m1G | RNA | tRNA | 37 | CAA | CAA | tRNALeuCAA | anticodon-loop | Nucleus | ||
G:m1G | RNA | tRNA | 37 | UAA | UAA | tRNALeuUAA | anticodon-loop | Nucleus | ||
G:m1G | RNA | tRNA | 37 | UGG | UGG | tRNAProUGG | anticodon-loop | Nucleus | ||
G:m1G | RNA | tRNA | 37 | GUG | GUG | tRNAHisGUG | anticodon-loop | Nucleus | ||
G:m1G | RNA | tRNA | 37 | GUC | GUC | tRNAAspGUC | anticodon-loop | Nucleus | ||
G:m1G | RNA | tRNA | 37 | GAA | GAA | tRNAPheGAA | anticodon-loop | Nucleus | ||
G:m1G | RNA | tRNA | 37 | GAG | GAG | tRNALeuGAG | anticodon-loop | Nucleus |
Alpha Fold Pdb Files | AF-P38793-F1.pdb   |
Alpha Fold Pdbx/mmCIF Files | AF-P38793-F1.cif   |
DSSP Secondary Structures | P38793.dssp   |
Title | Authors | Journal | Details | ||
---|---|---|---|---|---|
Biosynthesis of wybutosine, a hyper-modified nucleoside in eukaryotic phenylalanine tRNA. | Noma A, Kirino Y, Ikeuchi Y, Suzuki T | EMBO J | [details] | 16642040 | - |
A primordial tRNA modification required for the evolution of life? | Bjork GR, Jacobsson K, Nilsson K, Johansson MJ, Bystrom AS, Persson OP | EMBO J | [details] | 11226173 | - |
Control of catalytic cycle by a pair of analogous tRNA modification enzymes. | Christian T, Lahoud G, Liu C, Hou YM | J Mol Biol | [details] | 20452364 | - |
Mechanism of N-methylation by the tRNA m1G37 methyltransferase Trm5. | Christian T, Lahoud G, Liu C, Hoffmann K, Perona JJ, Hou YM | RNA | [details] | 20980671 | - |
Yeast mitochondrial initiator tRNA is methylated at guanosine 37 by the Trm5-encoded tRNA (guanine-N1-)-methyltransferase. | Lee C, Kramer G, Graham DE, Appling DR | J Biol Chem | [details] | 17652090 | - |
_SGD_ |
_PubMed_ |