Modomics - A Database of RNA Modifications

ID Card:

Full name: dimethyladenosine transferase
Synonym: DIMT1
GI: 1143076922
UniProt: Q9UNQ2
Structures: | 1ZQ9 | 6W6C | 6W6F | 7MQA |
Alpha Fold Predicted Structure: AF-Q9UNQ2-F1
Enzyme type: methyltransferase
Position of modification - modification: s:1850(1518) - m6,6A
s:1851(1519) - m6,6A


PDB Structures:


1ZQ9

Structure Description:

Title:
Classification:
Technique:

Abstract of the PDB Structure's related Publication:

rRNA-modifying enzymes participate in ribosome assembly. However, whether the catalytic activities of these enzymes are important for the ribosome assembly and other cellular processes is not fully understood. Here, we report the crystal structure of WT human dimethyladenosine transferase 1 (DIMT1), an 18 S rRNA N 6,6 -dimethyladenosine (m 2 6,6 A) methyltransferase, and results obtained with a catalytically inactive DIMT1 variant. We found that DIMT1 +/- heterozygous HEK 293T cells have a significantly decreased 40S fraction and reduced protein synthesis but no major changes in m 2 6,6 A levels in 18 S rRNA. Expression of a catalytically inactive variant, DIMT1-E85A, in WT and DIMT1 +/- cells significantly decreased m 2 6,6 A levels in 18S rRNA, indicating a dominant-negative effect of this variant on m 2 6,6 A levels. However, expression of the DIMT1-E85A variant restored the defects in 40S levels. Of note, unlike WT DIMT1, DIMT1-E85A could not revert the defects in protein translation. We found that the differences between this variant and the WT enzyme extended to translation fidelity and gene expression patterns in DNA damage response pathways. These results suggest that the catalytic activity of DIMT1 is involved in protein translation and that the overall protein scaffold of DIMT1, regardless of the catalytic activity on m 2 6,6 A in 18 S rRNA, is essential for 40S assembly.

Download RCSB-PDB Structures:

Pdb Files   1ZQ9.pdb   6W6C.pdb   6W6F.pdb   6X7U.pdb  
Pdbx/mmCIF Files   1ZQ9.cif   6W6C.cif   6W6F.cif   6X7U.cif   7MQA.cif  


Protein sequence:

MPKVKSGAIGRRRGRQEQRRELKSAGGLMFNTGIGQHILKNPLIINSIIDKAALRPTDVVLEVGPGTGNMTVKLLEKAKKVVACELDPRLVAELHKRVQGTPVASKLQVLVGDVLKTDLPFFDTCVANLPYQISSPFVFKLLLHRPFFRCAILMFQREFALRLVAKPGDKLYCRLSINTQLLARVDHLMKVGKNNFRPPPKVESSVVRIEPKNPPPPINFQEWDGLVRITFVRKNKTLSAAFKSSAVQQLLEKNYRIHCSVHNIIIPEDFSIADKIQQILTSTGFSDKRARSMDIDDFIRLLHGFNAEGIHFS

Comments:

DIMT1L and WBSCR22 - TRMT112 are the functional homologues of years Dim1 and Bud23-Trm112. These enzymes are reported to be required for distinct pre-rRNA processing reactions leading to the synthesis of 18S rRNA.Specifically, DIMT1L demethylates two adjacent N6-methyl adenosines (m6A) in the loop of a conserved hairpin near the 3'-end of 18S rRNA in the 40S particle DIMT1L is responsible for N6, N6 dimethylation at positions A1850 and A1851. The enzyme is required for distinct pre-rRNA processing reactions leading to the synthesis of 18S rRNA. It has been furtherly demonstrated that, in human cells, as in budding yeast, ribosome biogenesis requires the presence of the modification enzyme rather than its RNA-modifying catalytic activity (Zorbas et al. 2015 ).




Reaction Substrate SubstrateType Position (Anti)Codon Modified (Anti)Codon Amino Acid Change Transcript Name Transcript Region Cellular Localization References
A:m6A RNA rRNA 1779 small rRNA subunit 18S Nucleolus 25851604   
A:m6A RNA rRNA 1780 small rRNA subunit 18S Nucleolus 25851604   

Alpha Fold Predicted Structure:






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Protein sequence:

M P K V K S G A I G R R R G R Q E Q R R E L K S A G G L M F N T G I G Q H I L K N P L I I N S I I D K A A L R P T D V V L E V G P G T G N M T V K L L E K A K K V V A C E L D P R L V A E L H K R V Q G T P V A S K L Q V L V G D V L K T D L P F F D T C V A N L P Y Q I S S P F V F K L L L H R P F F R C A I L M F Q R E F A L R L V A K P G D K L Y C R L S I N T Q L L A R V D H L M K V G K N N F R P P P K V E S S V V R I E P K N P P P P I N F Q E W D G L V R I T F V R K N K T L S A A F K S S A V Q Q L L E K N Y R I H C S V H N I I I P E D F S I A D K I Q Q I L T S T G F S D K R A R S M D I D D F I R L L H G F N A E G I H F S

Secondary Structure Alphabet

  • G: 3-turn helix (310helix)
  • H: α-helix
  • I: 𝝅-helix (5 - turn helix)
  • T: Hydrogen Bonded Turn
  • B: β-sheet
  • S: Bend
  • C: Coil (residues not present in any of the above conformations)
  • N: Not assigned

Download PDB Structures & DSSP Secondary Structures:

Alpha Fold Pdb Files   AF-Q9UNQ2-F1.pdb  
Alpha Fold Pdbx/mmCIF Files   AF-Q9UNQ2-F1.cif  
DSSP Secondary Structures   Q9UNQ2.dssp  





Publications:

Title Authors Journal Details PubMed Id DOI
The human 18S rRNA base methyltransferases DIMT1L and WBSCR22-TRMT112 but not rRNA modification are required for ribosome biogenesis. Zorbas C, Nicolas E, Wacheul L, Huvelle E, Heurgué-Hamard V, Lafontaine DL. Mol Biol Cell [details] 25851604 10.1091/mbc.E15-02-0073